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CATECHOLBORANE

  • CAS No.: 274-07-7
  • Purity: 99%
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CATECHOLBORANE 274-07-7 with purity >99% Low price in stock

  • Molecular Formula: C6H5BO2
  • Molecular Weight: 119.915
  • Appearance/Colour: clear colorless solution 
  • Vapor Pressure: 17.554mmHg at 25°C 
  • Melting Point: 12 °C(lit.) 
  • Refractive Index: n20/D 1.507(lit.)  
  • Boiling Point: 121.385 °C at 760 mmHg 
  • Flash Point: 27.213 °C 
  • PSA: 18.46000 
  • Density: 1.125g/mLat 25°C(lit.) 
  • LogP: 0.72430 

CATECHOLBORANE(Cas 274-07-7) Usage

Purification Methods

It is a moisture-sensitive flammable liquid which is purified by distillation in a vacuum under a N2 atmosphere and stored under N2 at 0-4o. It liberates H2 when added to H2O or MeOH. A solution in THF, after 25hours at 25o, has residual hydride of 95% (under N2) and 80% (under air) [Brown & Gupta J Am Chem Soc 97 5249 1975].

InChI:InChI=1/C6H5BO2/c1-2-4-6-5(3-1)8-7-9-6/h1-4,7H

274-07-7 Relevant articles

Boryl-dihydrideborate osmium complexes: Preparation, structure, and dynamic behavior in solution

Esteruelas, Miguel A.,López, Ana M.,Mora, Malka,O?ate, Enrique

, p. 941 - 946 (2015)

The metal fragment Os(CO)(PiPr3)2 stabil...

New economical, convenient procedures for the synthesis of catecholborane

Kanth, Josyula V.B.,Periasamy, Mariappan,Brown, Herbert C.

, p. 550 - 553 (2000)

Catecholborane was conveniently synthesi...

Kinetics of the reduction of pinacolone by borane-dimethyl sulfide and catecholborane in THF

Eckhardt, Conrad,Jockel, Holger,Schmidt, Reinhard

, p. 2155 - 2162 (1999)

The kinetics of the reduction of the ket...

Reactivity

Hartwig, John F.,He, Xiaoming

, p. 315 - 317 (1996)

-

-

May,S.W. et al.

, p. 2017 - 2024 (1977)

-

Synthesis of Unsymmetrical Diboron(5) Compounds and Their Conversion to Diboron(5) Cations

Cid, Jessica,Hermann, Alexander,Radcliffe, James E.,Curless, Liam D.,Braunschweig, Holger,Ingleson, Michael J.

, p. 1992 - 1998 (2018)

Reaction of the bis-catecholatodiboron-N...

Trans -2 - substituted cycloalkyl three fluoro potassium borate synthesis method (by machine translation)

-

Paragraph 0022, (2019/04/04)

The invention discloses trans - 2 - subs...

Synthesis of catechol-, pinacol-, and neopentylglycolborane through the heterogeneous catalytic B-B hydrogenolysis of diboranes(4)

Braunschweig, Holger,Guethlein, Frank,Mailaender, Lisa,Marder, Todd B.

, p. 14831 - 14835 (2013/11/06)

A new synthetic approach to hydroboranes...

274-07-7 Process route

(CO)5Mn(BO<sub>2</sub>C<sub>6</sub>H<sub>4</sub>)
172266-59-0

(CO)5Mn(BO2 C6 H4 )

benzene
71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1

benzene

dimanganese decacarbonyl
10170-69-1

dimanganese decacarbonyl

2-phenyl-1,3,2-benzodioxaborole
5747-23-9

2-phenyl-1,3,2-benzodioxaborole

benzo[1,3,2]dioxaborole
274-07-7

benzo[1,3,2]dioxaborole

Conditions
Conditions Yield
In benzene; Irradiation (UV/VIS); irradiation (6 h, Hanovia Hg lamp);
45%
10%
(CO)5Re(BO<sub>2</sub>C<sub>6</sub>H<sub>4</sub>)
172266-60-3

(CO)5Re(BO2 C6 H4 )

benzene
71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1

benzene

decacarbonyldirhenium<sup>(0)</sup>
14285-68-8

decacarbonyldirhenium(0)

[Re3(μ-H)3(CO)12]
73463-62-4

[Re3(μ-H)3(CO)12]

2-phenyl-1,3,2-benzodioxaborole
5747-23-9

2-phenyl-1,3,2-benzodioxaborole

benzo[1,3,2]dioxaborole
274-07-7

benzo[1,3,2]dioxaborole

Conditions
Conditions Yield
In benzene; Irradiation (UV/VIS); irradiation (3 h);
50%
5%

274-07-7 Upstream products

  • 120-80-9
    120-80-9

    benzene-1,2-diol

  • 37737-62-5
    37737-62-5

    tris(catecholato)diboron

  • 694-53-1
    694-53-1

    phenylsilane

  • 94500-04-6
    94500-04-6

    BH3 *THF-d8

274-07-7 Downstream products

  • 5294-96-2
    5294-96-2

    2-(Benzo[1,3,2]dioxaborol-2-yloxy)-benzaldehyde

  • 32999-14-7
    32999-14-7

    2-cyclopentyl-benzo[1,3,2]dioxaborole

  • 32999-09-0
    32999-09-0

    2-cyclohexylbenzo-[d][1,3,2]dioxaborole

  • 37490-23-6
    37490-23-6

    (E)-1-vinyl-2-cyclohexyl-catecholborane

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