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CATECHOLBORANE 274-07-7 with purity >99% Low price in stock
- Molecular Formula: C6H5BO2
- Molecular Weight: 119.915
- Appearance/Colour: clear colorless solution
- Vapor Pressure: 17.554mmHg at 25°C
- Melting Point: 12 °C(lit.)
- Refractive Index: n20/D 1.507(lit.)
- Boiling Point: 121.385 °C at 760 mmHg
- Flash Point: 27.213 °C
- PSA: 18.46000
- Density: 1.125g/mLat 25°C(lit.)
- LogP: 0.72430
CATECHOLBORANE(Cas 274-07-7) Usage
|
Purification Methods |
It is a moisture-sensitive flammable liquid which is purified by distillation in a vacuum under a N2 atmosphere and stored under N2 at 0-4o. It liberates H2 when added to H2O or MeOH. A solution in THF, after 25hours at 25o, has residual hydride of 95% (under N2) and 80% (under air) [Brown & Gupta J Am Chem Soc 97 5249 1975]. |
InChI:InChI=1/C6H5BO2/c1-2-4-6-5(3-1)8-7-9-6/h1-4,7H
274-07-7 Relevant articles
Boryl-dihydrideborate osmium complexes: Preparation, structure, and dynamic behavior in solution
Esteruelas, Miguel A.,López, Ana M.,Mora, Malka,O?ate, Enrique
, p. 941 - 946 (2015)
The metal fragment Os(CO)(PiPr3)2 stabil...
New economical, convenient procedures for the synthesis of catecholborane
Kanth, Josyula V.B.,Periasamy, Mariappan,Brown, Herbert C.
, p. 550 - 553 (2000)
Catecholborane was conveniently synthesi...
Kinetics of the reduction of pinacolone by borane-dimethyl sulfide and catecholborane in THF
Eckhardt, Conrad,Jockel, Holger,Schmidt, Reinhard
, p. 2155 - 2162 (1999)
The kinetics of the reduction of the ket...
Reactivity
Hartwig, John F.,He, Xiaoming
, p. 315 - 317 (1996)
-
-
May,S.W. et al.
, p. 2017 - 2024 (1977)
-
Synthesis of Unsymmetrical Diboron(5) Compounds and Their Conversion to Diboron(5) Cations
Cid, Jessica,Hermann, Alexander,Radcliffe, James E.,Curless, Liam D.,Braunschweig, Holger,Ingleson, Michael J.
, p. 1992 - 1998 (2018)
Reaction of the bis-catecholatodiboron-N...
Trans -2 - substituted cycloalkyl three fluoro potassium borate synthesis method (by machine translation)
-
Paragraph 0022, (2019/04/04)
The invention discloses trans - 2 - subs...
Synthesis of catechol-, pinacol-, and neopentylglycolborane through the heterogeneous catalytic B-B hydrogenolysis of diboranes(4)
Braunschweig, Holger,Guethlein, Frank,Mailaender, Lisa,Marder, Todd B.
, p. 14831 - 14835 (2013/11/06)
A new synthetic approach to hydroboranes...
274-07-7 Process route
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172266-59-0
(CO)5Mn(BO2 C6 H4 )
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-
71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene
-
-
10170-69-1
dimanganese decacarbonyl
-
-
5747-23-9
2-phenyl-1,3,2-benzodioxaborole
-
-
274-07-7
benzo[1,3,2]dioxaborole
| Conditions | Yield |
|---|---|
|
In
benzene;
Irradiation (UV/VIS); irradiation (6 h, Hanovia Hg lamp);
|
45%
10% |
-
-
172266-60-3
(CO)5Re(BO2 C6 H4 )
-
-
71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene
-
-
14285-68-8
decacarbonyldirhenium(0)
-
-
73463-62-4
[Re3(μ-H)3(CO)12]
-
-
5747-23-9
2-phenyl-1,3,2-benzodioxaborole
-
-
274-07-7
benzo[1,3,2]dioxaborole
| Conditions | Yield |
|---|---|
|
In
benzene;
Irradiation (UV/VIS); irradiation (3 h);
|
50%
5% |
274-07-7 Upstream products
-
120-80-9
benzene-1,2-diol
-
37737-62-5
tris(catecholato)diboron
-
694-53-1
phenylsilane
-
94500-04-6
BH3 *THF-d8
274-07-7 Downstream products
-
5294-96-2
2-(Benzo[1,3,2]dioxaborol-2-yloxy)-benzaldehyde
-
32999-14-7
2-cyclopentyl-benzo[1,3,2]dioxaborole
-
32999-09-0
2-cyclohexylbenzo-[d][1,3,2]dioxaborole
-
37490-23-6
(E)-1-vinyl-2-cyclohexyl-catecholborane
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