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3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL

  • CAS No.:34819-86-8
  • Purity:99%
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1.What is the 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL ?

A DNA-binding agent.

2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl bromide
5158-64-5

2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl bromide

3,4-di-O-acetyl-6-deoxy-L-glucal
34819-86-8

3,4-di-O-acetyl-6-deoxy-L-glucal

Conditions
Conditions Yield
With zinc; sodium acetate; acetic acid; In tetrahydrofuran; at 20 ℃; for 2.5h;
93%
With acetic acid; zinc; (N,N'-ethylenebis(salicylideneaminato))oxovanadium(IV); In acetonitrile; for 1.08333h;
91%
With β‐cyclodextrin; zinc; In water; at 20 ℃; for 0.5h; Sonication;
91%
With manganese; chloro-trimethyl-silane; bis(cyclopentadienyl)titanium dichloride; In tetrahydrofuran; at 20 ℃; for 12h;
87%
With sodium dihydrogenphosphate; zinc; In ethyl acetate; at 20 ℃; for 3h;
87%
bis(cyclopentadienyl)titanium dichloride; manganese; In tetrahydrofuran; at 20 ℃;
84%
With ammonium chloride; zinc; In acetonitrile; at 50 ℃; for 0.75h; Inert atmosphere;
81%
With amalgamated magnesium; In N,N-dimethyl-formamide; a) 0 deg C, 0.5 h, b) 2 h;
78%
With sodium dihydrogenphosphate; zinc; In ethyl acetate; at 20 ℃; for 12h;
4.377 g
2,3,4-tri-O-acetyl-6-deoxy-beta-L-mannopyranosyl bromide
39524-38-4

2,3,4-tri-O-acetyl-6-deoxy-beta-L-mannopyranosyl bromide

3,4-di-O-acetyl-6-deoxy-L-glucal
34819-86-8

3,4-di-O-acetyl-6-deoxy-L-glucal

Conditions
Conditions Yield
With aluminium amalgam; In tetrahydrofuran; water; for 3h; Ambient temperature;
82%
2,3,4-tri-O-acetyl-6-deoxy-beta-L-mannopyranosyl bromide; With sodium dihydrogenphosphate; zinc; In ethyl acetate; for 0.166667h;
With phosphoric acid; In ethyl acetate; at 60 ℃; for 1h;
72%

2.What is the CAS number for 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL ?

The CAS number of 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL is 34819-86-8.

More information of 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL 34819-86-8 are:

CAS?Number

34819-86-8

Density

1.116 g/mL at 25 °C(lit.)

Boiling Point

68-69 °C0.06 mm Hg(lit.)

Flash Point

>230 °F

Vapor Pressure

0.00149mmHg at 25°C

Refractive Index

n20/D 1.454(lit.)

HS CODE

29400090

PSA

61.83000

LogP

0.78220

3.What are another words for 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL ?

Synonyms?for?3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL 34819-86-8:L-arabino-Hex-1-enitol,1,5-anhydro-2,6-dideoxy-, diacetate (9CI); 3,4-Di-O-acetyl-6-deoxy-L-glucal;3,4-Di-O-acetyl-L-rhamnal; 6-Deoxy-L-glucal diacetate; Di-O-acetyl-L-rhamnal;Diacetyl-L-rhamnal; L-Rhamnal diacetate

4.What is the molecular formula of 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL?

The chemical formula of ?3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL is?C10H14 O5 which containing 10 Carbon atoms,14 Hydrogen atoms and 5 Oxygen atoms,and the molecular weight of??3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL?is 214.218.

5.What is 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL (34819-86-8) used for?

3,4-Di-O-acetyl-6-deoxy-L-glucal (also known as 3,4-di-O-acetyl-L-rhamnal or L-rhamnal diacetate) is a per-O-acetylglycal derivative that serves as a substrate in AuCl3-catalyzed Ferrier reactions, enabling the synthesis of 2,3-unsaturated glycosides under mild conditions. 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL, along with other per-O-acetylglycals, is efficiently activated by AuCl3 to react with various nucleophiles, including alcohols, thiols, and C-nucleophiles. The study highlights its role in exploring β-selectivity in glycoside formation, though the focus is primarily on the catalytic process rather than the specific properties of 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL itself. **Return:** 3,4-Di-O-acetyl-6-deoxy-L-glucal is a per-O-acetylglycal used as a substrate in AuCl3-catalyzed Ferrier reactions, facilitating the synthesis of 2,3-unsaturated glycosides under ambient conditions. It reacts with diverse nucleophiles, contributing to studies on β-selectivity in glycoside formation.

InChI:InChI=1/C10H14O5/c1-6-10(15-8(3)12)9(4-5-13-6)14-7(2)11/h4-6,9-10H,1-3H3/t6-,9-,10-/m0/s1

Relevant articles related to 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL:

Article

Source

-

Iselin,Reichstein

, p. 1146,1148 (1944)

Expeditious Synthesis of a Tetrasaccharide Repeating Unit of the O-Antigen of Escherichia coli O163

Karki, Geeta,Kumar, Harikesh,Rajan, Remya,Mandal, Pintu Kumar

, p. 2581 - 2586 (2016)

6.Buy 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL with the best price .

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