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Quality products?make an important contribution to long-term revenue and profitability. Reputable factory supply 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL 34819-86-8 in stock with high standard
1.What is the 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL ?
A DNA-binding agent.
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5158-64-5
2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl bromide
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-
34819-86-8
3,4-di-O-acetyl-6-deoxy-L-glucal
| Conditions | Yield |
|---|---|
|
With
zinc; sodium acetate; acetic acid;
In
tetrahydrofuran;
at 20 ℃;
for 2.5h;
|
93% |
|
With
acetic acid; zinc;
(N,N'-ethylenebis(salicylideneaminato))oxovanadium(IV);
In
acetonitrile;
for 1.08333h;
|
91% |
|
With
β‐cyclodextrin; zinc;
In
water;
at 20 ℃;
for 0.5h;
Sonication;
|
91% |
|
With
manganese; chloro-trimethyl-silane;
bis(cyclopentadienyl)titanium dichloride;
In
tetrahydrofuran;
at 20 ℃;
for 12h;
|
87% |
|
With
sodium dihydrogenphosphate; zinc;
In
ethyl acetate;
at 20 ℃;
for 3h;
|
87% |
|
bis(cyclopentadienyl)titanium dichloride; manganese;
In
tetrahydrofuran;
at 20 ℃;
|
84% |
|
With
ammonium chloride; zinc;
In
acetonitrile;
at 50 ℃;
for 0.75h;
Inert atmosphere;
|
81% |
|
With
amalgamated magnesium;
In
N,N-dimethyl-formamide;
a) 0 deg C, 0.5 h, b) 2 h;
|
78% |
|
With
sodium dihydrogenphosphate; zinc;
In
ethyl acetate;
at 20 ℃;
for 12h;
|
4.377 g |
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39524-38-4
2,3,4-tri-O-acetyl-6-deoxy-beta-L-mannopyranosyl bromide
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34819-86-8
3,4-di-O-acetyl-6-deoxy-L-glucal
| Conditions | Yield |
|---|---|
|
With
aluminium amalgam;
In
tetrahydrofuran; water;
for 3h;
Ambient temperature;
|
82% |
|
2,3,4-tri-O-acetyl-6-deoxy-beta-L-mannopyranosyl bromide;
With
sodium dihydrogenphosphate; zinc;
In
ethyl acetate;
for 0.166667h;
With
phosphoric acid;
In
ethyl acetate;
at 60 ℃;
for 1h;
|
72% |
2.What is the CAS number for 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL ?
The CAS number of 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL is 34819-86-8.
More information of 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL 34819-86-8 are:
|
CAS?Number |
34819-86-8 |
|
Density |
1.116 g/mL at 25 °C(lit.) |
|
Boiling Point |
68-69 °C0.06 mm Hg(lit.) |
|
Flash Point |
>230 °F |
|
Vapor Pressure |
0.00149mmHg at 25°C |
|
Refractive Index |
n20/D 1.454(lit.) |
|
HS CODE |
29400090 |
|
PSA |
61.83000 |
|
LogP |
0.78220 |
3.What are another words for 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL ?
Synonyms?for?3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL 34819-86-8:L-arabino-Hex-1-enitol,1,5-anhydro-2,6-dideoxy-, diacetate (9CI); 3,4-Di-O-acetyl-6-deoxy-L-glucal;3,4-Di-O-acetyl-L-rhamnal; 6-Deoxy-L-glucal diacetate; Di-O-acetyl-L-rhamnal;Diacetyl-L-rhamnal; L-Rhamnal diacetate
4.What is the molecular formula of 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL?
The chemical formula of ?3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL is?C10H14 O5 which containing 10 Carbon atoms,14 Hydrogen atoms and 5 Oxygen atoms,and the molecular weight of??3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL?is 214.218.
5.What is 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL (34819-86-8) used for?
3,4-Di-O-acetyl-6-deoxy-L-glucal (also known as 3,4-di-O-acetyl-L-rhamnal or L-rhamnal diacetate) is a per-O-acetylglycal derivative that serves as a substrate in AuCl3-catalyzed Ferrier reactions, enabling the synthesis of 2,3-unsaturated glycosides under mild conditions. 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL, along with other per-O-acetylglycals, is efficiently activated by AuCl3 to react with various nucleophiles, including alcohols, thiols, and C-nucleophiles. The study highlights its role in exploring β-selectivity in glycoside formation, though the focus is primarily on the catalytic process rather than the specific properties of 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL itself. **Return:** 3,4-Di-O-acetyl-6-deoxy-L-glucal is a per-O-acetylglycal used as a substrate in AuCl3-catalyzed Ferrier reactions, facilitating the synthesis of 2,3-unsaturated glycosides under ambient conditions. It reacts with diverse nucleophiles, contributing to studies on β-selectivity in glycoside formation.
InChI:InChI=1/C10H14O5/c1-6-10(15-8(3)12)9(4-5-13-6)14-7(2)11/h4-6,9-10H,1-3H3/t6-,9-,10-/m0/s1
Relevant articles related to 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL:
|
Article |
Source |
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Iselin,Reichstein , p. 1146,1148 (1944) |
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Expeditious Synthesis of a Tetrasaccharide Repeating Unit of the O-Antigen of Escherichia coli O163 |
Karki, Geeta,Kumar, Harikesh,Rajan, Remya,Mandal, Pintu Kumar , p. 2581 - 2586 (2016) |
6.Buy 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL with the best price .
China Shilian Chemical Trading Co., Ltd. is a quality supplier of 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL. Our main goal is customer satisfaction. Contact us to negotiate the best price for your business on 3,4-DI-O-ACETYL-6-DEOXY-L-GLUCAL 34819-86-8.
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